ON THE MECHANISM OF OXIDATIVE POLYMERIZATION OF ANILINE

被引：80

作者：

GOSPODINOVA, N

TERLEMEZYAN, L

MOKREVA, P

KOSSEV, K

机构：

[1] Institute of Polymers, Bulgarian Academy of Sciences

来源：

POLYMER | 1993年 / 34卷 / 11期

关键词：

POLYANILINE; DISPERSION; ELECTRON ABSORPTION SPECTROSCOPY; MECHANISM OF POLYMERIZATION;

D O I：

10.1016/0032-3861(93)90834-W

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Oxidative polymerization of aniline in aqueous dispersion stabilized by poly(vinyl alcohol coacetate) was studied in situ by electron absorption spectroscopy. A mechanism is proposed, accounting for the dependence of the main polymerization steps (oxidation and reduction) on both the pH of the medium and the oxidation state of the chain.

引用

页码：2434 / 2437

页数：4

共 19 条

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