SYNTHESIS OF BUTENYNYLRUTHENIUM COMPLEXES FROM HYDRIDO, ALKENYL, OR ALKYNYL COMPLEXES

被引：52

作者：

SANTOS, A

LOPEZ, J

MATAS, L

ROS, J

GALAN, A

ECHAVARREN, AM

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM,E-08193 BARCELONA,SPAIN

[2] CSIC,INST QUIM ORGAN,E-28006 MADRID,SPAIN

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1021/om00034a070

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction Of Ru(CO)ClH(PPh3)3 with 1-alkynes in 1,2-dichloroethane under reflux conditions provides the coordinatively unsaturated butenynyl complexes [Ru{C(C=CR)=CHR}(CO)Cl(PPh3)2] in good yield. These and related butenynyl complexes were also prepared by starting from the corresponding alkenyl- or alkynylruthenium complexes. Hydrogenolysis of [Ru{C(C=CPh)=CHPh}(CO)Cl(PPh3)2] in the presence of pyridine gave (Z)-1,4-diphenylbutenyne and Ru(CO)ClH(py)(PPh3)2.

引用

页码：4215 / 4218

页数：4

共 26 条

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