AN ABNORMAL CLAISEN REARRANGEMENT OF 3,3-DIMETHYLALLYL OESTRONE ETHER

被引：15

作者：

JEFFERSON, A

SCHEINMANN, F

机构：

[1] Department of Chemistry, University of Salford, Salford, Lancashire

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 02期

关键词：

D O I：

10.1039/j39690000243

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rearrangement of 3,3-dimethylallyl oestrone ether gives mainly 2-(1,2-dimethylallyl)oestrone. The normal Claisen product, 2-(1,1-dimethylallyl)oestrone was not isolated until it was first trapped as its butyric ester. 2-(1,1-Dimethylallyl)oestrone was transformed into the 2-(1,2-dimethylallyl) isomer under the conditions of the Claisen rearrangement.

引用

页码：243 / +

页数：1

共 14 条

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