STEREOCHEMICAL STUDIES IN TRISNORLUPANE SERIES .2. STEREOSELECTIVITY OF REDUCTION OF A CYCLOPENTANONE BY COMPLEX METAL HYDRIDES

被引:1
作者
BADDELEY, GV
SHAO, WL
机构
[1] School of Chemistry, University of New South Wales, Kensington
关键词
D O I
10.1016/S0040-4020(01)96863-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The stereoselectivity of the reduction of 4,23,24-trisnor-(5βH)-5(4 → 3)-abeolupan-3-one (I) by complex metal hydrides, under a variety of conditions, is reported. This stereoselectivity is discussed in terms of theories relating to the similar reduction of cyclohexanones. © 1968.
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页码:6513 / &
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