KINETICS OF ELECTRON-TRANSFER BETWEEN METAL HEXACYANIDE COMPLEXES

被引：9

作者：

CHO, KC ^{[1
]}

CHAM, PM ^{[1
]}

CHE, CM ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 168卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(90)85625-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)6 3- 4-, Os(CN)6 3- 4- and Ru(CN)6 3- 4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus. © 1990.

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页码：361 / 364

页数：4

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