VERSATILE REACTIVITY OF 2-LITHIO-1,3-DITHIOLES - FORMATION OF SYMMETRICAL AND UNSYMMETRICAL TETRATHIAFULVALENES

被引：3

作者：

GIMBERT, Y

MORADPOUR, A

BITTNER, S

机构：

[1] UNIV PARIS 11,PHYS SOLIDE LAB,CNRS,UA2,F-91405 ORSAY,FRANCE

[2] BEN GURION UNIV NEGEV,DEPT CHEM,IL-84105 BEER SHEVA,ISRAEL

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 07期

关键词：

D O I：

10.1016/S0040-4039(00)94415-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reacting 2-lithio-1,3-dithioles with 1,3-dithiolium salts results in formation of both symmetrical and unsymmetrical tetrathiafulvalenes. The symmetrical tetra-thiafulvalenes are probably formed via a carbene intermediate which is generated by loss of an hydride from the 2-lithio-1,3-dithioles. © 1990.

引用

页码：1007 / 1010

页数：4

共 13 条

[1] A NEW HIGHLY-CONJUGATED TTF ANALOG - SYNTHESIS, ELECTROCHEMISTRY AND A CONDUCTING TCNQ COMPLEX OF 9,10-ANTHRACENEDIYLIDENE-2,2'-BIS(4,5-DIMETHYL-1,3-DITHIOLE) [J].