REACTIONS OF 2,2-DIFLUORO-4-METHYLNAPHTHO[1,2-E]-1,3,2-DIOXABORIN AND ITS [2,1-E] ISOMER WITH N,N-DIMETHYLFORMAMIDE

被引：34

作者：

REYNOLDS, GA

VANALLAN, JA

机构：

[1] Research Laboratories, Eastman Kodak Company, Rochester, New York

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1969年 / 6卷 / 03期

关键词：

D O I：

10.1002/jhet.5570060316

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compounds react with dimethylformamide in acetic anhydride to give dimethylamino‐vinyl derivatives which, on treatment with base, yield benzochroman‐4‐ones. The [1,2‐e] isomer reacts with the Vilsmeier complex to give 3‐formylbenzo[f]chrom‐4‐one and 9‐hydroxy‐1‐phenalenone, and the [2,1‐e]isomer gives 3‐formylbenzo[h]chrom‐4‐one. Copyright © 1969 Journal of Heterocyclic Chemistry

引用

页码：375 / +

页数：1

共 4 条

[1] The condensation of alpha-formylphenylacetonitriles with phenols Part I
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[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1931, : 1541 - 1546
[2] REARRANGEMENTS OF CHROMANONES AND DIHYDROCOUMARINS BY ALUMINIUM CHLORIDE
LOUDON, JD
RAZDAN, RK
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1954, (DEC): : 4299 - 4303
[3] REYNOLDS GT, IN PRESS
[4] REACTIONS OF 2,2-DIFLUORO-4-METHYLNAPHTHO[1,2-E]-1,3,2-DIOXABORIN AND ITS ISOMER WITH CARBONYL COMPOUNDS AND WITH ANILINE
VANALLAN, JA
REYNOLDS, GA
[J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1969, 6 (01) : 29 - &

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