METAL TEMPLATE REACTIONS .I. BENZILIC ACID REARRANGEMENT OF 2,2'-PYRIDIL AND RELATED COMPOUNDS PROMOTED BY NICKEL(2) AND COBALT(2) IONS

被引：11

作者：

BLACK, DSC

SRIVASTA.RC

机构：

[1] Department of Chemistry, Monash University, Clayton, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 07期

关键词：

D O I：

10.1071/CH9691439

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 2,2Ȳ-pyridil with methanolic nickel(II) and cobalt(II) acetates results in the formation of metal complexes of 2,2Ȳ-pyridilic acid. This benzilic acid rearrangement is undergone similarly by 2,2Ȳ- quinaldil but not by benzil, 2,2Ȳ-furil, or I-phenyl-2-(2Ȳ- pyridyl)ethane-1,2-dione. Possible mechanisms for this rearrangement are discussed. © 1969, CSIRO. All rights reserved.

引用

页码：1439 / &

共 24 条

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