PROPERTIES AND STRUCTURE OF LEAD HALOSILICATE GLASSES

被引：18

作者：

COON, J ^{[1
]}

SHELBY, JE ^{[1
]}

机构：

[1] ALFRED UNIV,NEW YORK STATE COLL CERAM,GLASS SCI LAB,ALFRED,NY 14802

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1990年 / 73卷 / 02期

关键词：

electrical properties; glass; halides; lead; silicates;

D O I：

10.1111/j.1151-2916.1990.tb06521.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The glass transformation temperature, thermal expansion coefficient, dc electrical conductivity, and IR transmission have been measured for four series of lead halosilicate glasses of the general composition (65–x)PbO·xPbX2·35 SiO2 (X=F, Cl, Br, I). Although results of these and other measurements suggest that the halide ions play similar structural roles in the glass, there appear to be significant differences in physical property behavior between glasses containing F− anions and those containing the other three halide anions. These results are explained by a proposed model incorporating both bridging and nonbridging halide species. Copyright © 1990, Wiley Blackwell. All rights reserved

引用

页码：379 / 382

页数：4

共 19 条

[1]

Anderson O. L., 1954, J AM CERAM SOC, V37, P573, DOI [DOI 10.1111/J.1151-2916.1954.TB13991.X, 10.1111/j.1151-2916.1954.tb13991.x]

[2] The constitution of lead oxide-silica glasses I, atomic arrangement [J].

Bair, GJ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1936, 19 :339-347

[3]

Cohen B. M., 1973, Journal of Non-Crystalline Solids, V12, P177, DOI 10.1016/0022-3093(73)90067-7

[4] PROPERTIES AND STRUCTURE OF LEAD FLUOROSILICATE GLASSES [J].

COON, J ;

SHELBY, JE .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (05) :354-357

[5] ELECTRICAL-CONDUCTION AND POLARIZATION IN LEAD SILICATE-GLASSES [J].

DUTTA, B ;

MAGRUDER, RH ;

WEEKS, RA ;

KINSER, DL .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1988, 71 (12) :1100-1103

[6]

HORTON M, UNPUB PROPERTIES STR

[7]

Hosono H., 1982, Yogyo-Kyokai-Shi, V90, P544, DOI 10.2109/jcersj1950.90.1045_544

[8]

HUGHES K, 1968, PHYS CHEM GLASSES, V9, P43

[9]

IMOKA M, 1980, YOGYO KYOKAISHI, V88, P141

[10]

IMOKA T, 1984, J NONCRYST SOLIDS, V64, P287

← 1 2 →