O-18 ISOTOPE SHIFTS ON THE C-13 NUCLEAR MAGNETIC-RESONANCE OF METAL-CARBONYL DERIVATIVES

被引：25

作者：

DARENSBOURG, DJ

机构：

[1] Department of Chemistry, Tulane University, New Orleans

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)85608-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxygen-18 isotope shifts on the natural abundance 13C spectra of oxygen-18 enriched samples of W(CO)8 and W(CO)5PPh3 have been observed to be 0.040 ppm (0.61 Hz at 15.03 MHz) upfield from that of a 13C nucleus bearing an oxygen-16 atom. © 1979.

引用

页码：C70 / C76

页数：7

共 19 条

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[2] HOMOGENEOUS CATALYSIS OF WATER GAS SHIFT REACTION USING RHODIUM CARBONYL IODIDE
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[3] REACTION OF IRON PENTACARBONYL WITH OXYGEN-18-ENRICHED HYDROXIDE - DECARBOXYLATION VS OXYGEN-EXCHANGE IN THE [FE(COOH]) INTERMEDIATE
DARENSBOURG, DJ
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WALKER, N
FROELICH, JA
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[J]. INORGANIC CHEMISTRY, 1979, 18 (05) : 1401 - 1402
[4] CHEMICAL AND IR SPECTRAL DETAILS OF REACTIONS INVOLVING STEREOSPECIFIC INCORPORATION OF O-18 INTO SUBSTITUTED MANGANESE AND RHENIUM CARBONYL DERIVATIVES VIA EXCHANGE-REACTIONS WITH H2O-18
DARENSBOURG, DJ
FROELICH, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (18) : 5940 - 5946
[5] DARENSBOURG DJ, 1977, ISRAEL J CHEM, V15, P247
[6] OXYGEN-EXCHANGE REACTIONS OF H2O-O-18 WITH HEXACARBONYL CATIONS OF MANGANESE AND RHENIUM
DARENSBOURG, DJ
FROELICH, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (14) : 4726 - 4729
[7] PREPARATION OF OXYGEN-18-LABELED DERIVATIVES OF [MN(CO)3(DIPHOS)H] VIA REACTION OF [MN(CO)4(DIPHOS)][PF6] WITH (H-2)-O-18 IN PRESENCE OF TRIETHYLAMINE - DECARBOXYLATION OF A [MN(COOH)] INTERMEDIATE
DARENSBOURG, DJ
FROELICH, JA
[J]. INORGANIC CHEMISTRY, 1978, 17 (11) : 3300 - 3302
[8] STEREOSPECIFIC INCORPORATION OF OXYGEN-18 INTO MANGANESE AND RHENIUM PENTACARBONYL DERIVATIVES VIA EXCHANGE-REACTIONS WITH H2O-18
DARENSBOURG, DJ
DREW, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (01) : 275 - 276
[9] PHASE-TRANSFER CATALYZED O-18 LABELING STUDIES OF CARBONYL LIGANDS IN NEUTRAL METAL-CARBONYL DERIVATIVES
DARENSBOURG, DJ
FROELICH, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (01) : 338 - 340
[10] DARENSBOURG DJ, 1979, ADV CHEM SER, V173, P106

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