SYNTHESES AND REACTIVITY OF NEW P-H DIBENZOBICYCLIC PHOSPHORANES BEARING HYDROXY-FUNCTION, ALKOXY-FUNCTION, OXO-FUNCTION, AMIDO-FUNCTION, AND DIHYDRIDO-FUNCTIONS AT THE PHOSPHORUS ATOM

被引：31

作者：

MURILLO, A ^{[1
]}

CHIQUETE, LM ^{[1
]}

JOSEPHNATHAN, P ^{[1
]}

CONTRERAS, R ^{[1
]}

机构：

[1] INST POLITECN NACL,CTR INVEST & ESTUDIOS AVANZADOS,DEPT QUIM,APARTADO 14-740,MEXICO CITY 07000,DF,MEXICO

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1990年 / 53卷 / 1-4期

关键词：

(P-H) dibenzobicyclic phosphoranes; substituted phosphoranes;

D O I：

10.1080/10426509008038016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new dibenzophosphoranes (1-6) bearing uncommon functions such as hydroxy-, alkoxy-, oxo-, amide- and dihydride- attached to the phosphorus atom have been prepared and characterized. The reactivities of the alkoxy derivative 1 and the amide 2 towards alcohols, amines, water and borane were studied mainly by 3IP NMR. The structure of the diphenoxyamine-bis-phoshorane 4 was established by single crystal X-ray diffraction studies. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：87 / 101

页数：15

共 14 条

[1] THE SYNTHESIS, STRUCTURE, AND CHEMISTRY OF 10-PN-3 SYSTEMS - TRICOORDINATE HYPERVALENT PNICTOGEN COMPOUNDS [J].