THE INFLUENCE OF ELECTRON DELOCALIZATION ON THE RATE CONSTANTS FOR COMPETING BAC2 AND E1CB ESTER HYDROLYSES

被引：6

作者：

INOUE, M ^{[1
]}

BRUICE, TC ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1981年 / 17期

关键词：

D O I：

10.1039/c39810000884

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

收藏

页码：884 / 886

页数：3

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共 6 条

[1] A MECHANISTIC CHANGE IN THE ALKALINE-HYDROLYSIS OF ESTERS OF FLUORENE-9-CARBOXYLIC ACID [J].

ALBORZ, M ;

DOUGLAS, KT .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (15) :728-730

[2]

BRUICE TC, 1970, J AM CHEM SOC, V92, P1370

[3] STRONG CONFORMATIONAL CONSEQUENCES OF HYPERCONJUGATION [J].

HOFFMANN, R ;

HEHRE, WJ ;

SALEM, L ;

SCHLEYER, PV ;

POPLE, JA ;

RADOM, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (17) :6221-&

[4] CARBANION MECHANISM OF ESTER HYDROLYSIS .2. OMICRON-NITROPHENYL ALPHA-CYANO-AND ALPHA-DIMETHYLSULFONIOACETATE ESTERS [J].

HOLMQUIST, B ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (11) :3003-+

[5] KINETICS OF PROTON TRANSFER FROM ALPHA CARBON OF ETHYL THIOACETATE AND ITS DIMETHYLIMINIUM DERIVATIVE [J].

LIENHARD, GE ;

WANG, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (14) :3781-&

[6] CARBANION MECHANISM (E1CB) OF ESTER HYDROLYSIS .3. SOME STRUCTURE-REACTIVITY STUDIES AND KETENE INTERMEDIATE [J].

PRATT, RF ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (20) :5956-&