LOWER BOUND FOR DISSOCIATION ENERGY OF HYDROGEN MOLECULE

被引：15

作者：

KOLOS, W

WOLNIEWICZ, L

机构：

[1] Department of Theoretical Chemistry, University of Warsaw

[2] Department of Theoretical Physics, N. Copernicus University, Torun

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 04期

关键词：

D O I：

10.1063/1.1672189

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An asymptotic formula for the diagonal nuclear motion corrections is derived for the hydrogen molecule, and a discussion is given of the errors which arise in the adiabatic dissociation energies from the failure of the adiabatic approximation to yield the exact energy of the dissociation products.

引用

页码：1417 / +

页数：1

共 11 条

[1]

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[2]

Born M., 1951, GOOTTINGER NACHR MN, V1

[3]

BUNKER PR, PRIVATE COMMUNICATIO

[4]

HERZBERG G, 1960, J MOL SPECTROSC, V5, P482