A RAMAN-SPECTROSCOPIC STUDY OF NICKEL(II) ACETATE, NI(CH3COO)2 AND ITS AQUEOUS AND METHANOLIC SOLUTIONS

被引：41

作者：

BICKLEY, RI

EDWARDS, HGM

ROSE, SJ

GUSTAR, R

机构：

[1] UNIV BRADFORD,DEPT CHEM & CHEM TECHNOL,BRADFORD BD7 1DP,W YORKSHIRE,ENGLAND

[2] DURACELL EUROPEAN TECH CTR,CRAWLEY RH10 2YY,W SUSSEX,ENGLAND

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 238卷

关键词：

D O I：

10.1016/0022-2860(90)85002-Z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A comprehensive Raman spestroscopic study of nickel(II) acetate tetrahydrate and its aqueous and methanolic solutions has been made. The v(Ni-O) stretching vibration of an aceto-nickel(II) complex has been identified. From comparisons with the Raman spectra of sodium acetate in the solid state and in aqueous and methanolic solutions, it is concluded that the acetato-nickel(II) complex is largely dissociated into acetate and hexa-aquo nickel(II) ions in aqueous solution under the experimental conditions. This evidence is discussed in the light of NMR and stability constant data for nickel(II) acetate. © 1990.

引用

页码：15 / 26

页数：12

共 22 条

[1] RELATION BETWEEN THE CRYSTAL-STRUCTURES OF SOME SALTS OF THE TYPE ME(OCOCH3)2 -NH2O AND THEIR ABILITY TO FORM MIXED-CRYSTALS OR DOUBLE SALTS (ME2+ =MG, CA, MN, CO, NI, CU, ZN, CD) [J].

BALAREW, C ;

STOILOVA, D .

JOURNAL OF SOLID STATE CHEMISTRY, 1981, 38 (02) :192-198

[2] STUDY OF THE BANDS ATTRIBUTABLE TO CRYSTALLIZATION WATER IN HYDRATED METAL ACETATES [J].

BARALDI, P ;

FABBRI, G .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1981, 37 (02) :89-92

[3]

BICKLEY RI, IN PRESS

[4] 3-DIMENSIONAL STUDY OF CRYSTAL STRUCTURE OF NICKEL ACETATE TETRAHYDRATE [J].

DOWNIE, TC ;

HARRISON, W ;

RAPER, ES ;

HEPWORTH, MA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (MAR) :706-&

[5] A QUANTITATIVE RAMAN-SPECTROSCOPIC INVESTIGATION OF HYDROGEN-BONDING IN ETHANOL AND ETHANOL-D1 [J].

EDWARDS, HGM ;

FARWELL, DW ;

JONES, A .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1989, 45 (11) :1165-1171

[6]

FUENTES R, 1975, INORG CHEM, V14, P170

[7]

GRIGOREV AI, 1963, ZH NEORG KHIM+, V8, P409

[8] THE VIBRATIONAL SPECTRA OF THE FORMATE, ACETATE, AND OXALATE IONS [J].

ITO, K ;

BERNSTEIN, HJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1956, 34 (02) :170-178

[9] INFRARED SPECTRA OF CH3COONA AND CD3COONA AND ASSIGNMENTS OF VIBRATIONAL FREQUENCIES [J].

JONES, LH ;

MCLAREN, E .

JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (11) :1796-1800

[10]

MARCUS Y, 1966, REC CHEM PROG, V27, P105

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