CATALYSIS OF THE EPOXIDATION OF OLEFINS

被引：19

作者：

LASZLO, P

LEVART, M

SINGH, GP

机构：

[1] Laboratoire de chimie fine, biomimétique et aux interfaces - Ecole Polytechnique

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 27期

关键词：

MCPBA SUBSTITUTE; VANADIUM OXIDE; TERT-BUTYLHYDROPEROXIDE; SELECTIVITY;

D O I：

10.1016/S0040-4039(00)79712-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By analogy between the oxo forms of vanadium (V) and iron (IV), the latter being the active species in oxidations by cytochrome P-450, the system constituted by vanadium oxide (catalyst) and t-butylhydroperoxide (oxidant) gives good results in the conversion of olefins to the corresponding epoxides.

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页码：3167 / 3168

页数：2

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