HYDROTALCITE-PROMOTED EPOXIDATION OF ELECTRON-DEFICIENT ALKENES WITH HYDROGEN-PEROXIDE

被引：99

作者：

CATIVIELA, C

FIGUERAS, F

FRAILE, JM

GARCIA, JI

MAYORAL, JA

机构：

[1] UNIV ZARAGOZA,FAC CIENCIAS,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM ORGAN,E-50009 ZARAGOZA,SPAIN

[2] INST RECH CATALYSE,F-69626 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 23期

关键词：

D O I：

10.1016/0040-4039(95)00675-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthetic anionic clay, hydrotalcite (Mg/Al = 2.8), promotes the epoxidation of electron-deficient alkenes with H2O2. With open-chain, alpha,beta-unsaturated carbonyl compounds 3-hydroxy-1,2-dioxolanes are also obtained.

引用

页码：4125 / 4128

页数：4

共 14 条

[1] Smith, Solid Supports and Catalysts in Organic Synthesis, (1992)
[2] Cornelis, Laszlo, Molding Clays into Efficient Catalysts, Synlett, (1994)
[3] Clark, Cork, Robertson, Fluoride ion catalysed Michael reactions., Chemistry Letters, (1983)
[4] Butters, Solid Supports and Catalysts in Organic Synthesis, (1992)
[5] Nakano, Niki, Kinouchi, Miyamae, Igarashi, Bull. Chem. Soc. Jpn., 65, (1992)
[6] Yamawaki, Ando, Hanafusa, N-Alkylation of amides and N-heterocycles with potassium fluoride on alumina., Chemistry Letters, (1981)
[7] Yadav, Kapoor, Tetrahedron Lett., 35, (1994)
[8] Sukata, The selective N-monoalkylation of amides with alkyl halides in the presence of alumina and KOH., Bulletin of the Chemical Society of Japan, 58, (1985)
[9] Corma, Synthesis, Characterization and Novel Applications of Molecular Sieve Materials, Mat. Res. Symp. Proc., 17, (1991)
[10] Reichle, Kang, Everhardt, J. Catal., 101, (1986)

← 1 2 →