LINEAR DELTAH-DELTAV-C=O RELATION FOR ETHYL ACETATE ADDUCTS AND ITS SIGNIFICANCE FOR DONOR-ACCEPTOR INTERACTIONS

被引：81

作者：

BROWN, DG

DRAGO, RS

BOLLES, TF

机构：

[1] W. A. Noyes Laboratory, University of Illinois, Urbana, Illinois

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 21期

关键词：

D O I：

10.1021/ja01023a010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A linear correlation has been found between the ethyl acetate carbonyl frequency shift upon complexation and the enthalpy of adduct formation for a series of Lewis acids. This phenomenon is discussed with respect to the energetics of adduct formation. A modified idea of the traditional reorganization energy is necessary to explain the correlation. An alternative way to look at the energetics of adduct formation is introduced using the concepts of unit basicity and unit acidity. © 1968, American Chemical Society. All rights reserved.

引用

页码：5706 / &

共 38 条

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