STRUCTURE OF TRIPHENYLTIN CHLORIDE TRIPHENYLPHOSPHINE OXIDE (1/1) COMPLEX

被引：23

作者：

NG, SW ^{[1
]}

DAS, VGK ^{[1
]}

机构：

[1] UNIV MALAYA,DEPT CHEM,KUALA LUMPUR 59100,MALAYSIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192001306

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chloro(triphenyl)(triphenylphosphine oxide)tin, [SnCl{(C6H5)3PO}(C6H5)3], M(r) = 663.76, monoclinic, P2(1)/c, a = 10.671 (1), b = 11.777 (2), c = 25.494 (1) angstrom, beta = 98.148 (5)-degrees, V = 3171.5 (7) angstrom3, Z = 4, D(x) = 1.390 g cm-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = 9.67 cm-1, F(000) = 1344, T = 298 K, R = 0.033 for 3327 [I greater-than-or-equal-to 3sigma(I)] reflections. Triphenyltin chloride forms a molecular complex with triphenylphosphine oxide in which Sn-Cl = 2.470 (2) and Sn-O = 2.391 (4) angstrom. The geometry of Sn is a trans-C3SnClO trigonal bipyramid.

引用

页码：1839 / 1841

页数：3

共 7 条

[1]

BOKII NG, 1970, ZH STRUKT KHIM, V11, P895

[2]

FAIR CK, 1990, MOLEN STRUCTURE DETE

[3]

MAIN P, 1982, MULTAN SYSTEM COMPUT

[4] SPECTROSCOPIC PROPERTIES AND X-RAY CRYSTAL-STRUCTURE OF A DINUCLEAR TIN ADDUCT - MU-BIS(DIPHENYLPHOSPHINYL)ETHANEBIS(CHLOROTRIPHENYLTIN) [J].