STRUCTURAL VARIATIONS OBSERVED IN THE [BI(O2CCF3)4PH]2- ANION - SELECTIVE CATION - ANION INTERACTIONS THROUGH HYDROGEN-BONDS

被引：9

作者：

BREEZE, SR ^{[1
]}

WANG, SN ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 04期

关键词：

D O I：

10.1002/anie.199305891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The length of the carbon bridge between the two positively charged nitrogen centers in dication 1 influences the coordination sphere of the Bi center in the title anion. The change from square‐pyramidal (n = 3, shown schematically on the right) to pentagonal‐pyramidal (n = 2) is attributed to the formation of NHO hydrogen bonds. (Formula Presented.) (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：589 / 591

页数：3

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