USE OF WATER AS AN INTERNAL STANDARD IN THE DIRECT MONITORING OF EMULSION POLYMERIZATION BY FIBEROPTIC RAMAN-SPECTROSCOPY

被引：45

作者：

WANG, C ^{[1
]}

VICKERS, TJ ^{[1
]}

MANN, CK ^{[1
]}

机构：

[1] FLORIDA STATE UNIV,DEPT CHEM,TALLAHASSEE,FL 32306

来源：

APPLIED SPECTROSCOPY | 1993年 / 47卷 / 07期

关键词：

EMULSION POLYMERIZATION; RAMAN SPECTROSCOPY; DIRECT ANALYSIS; METHYL METHACRYLATE; INTERNAL STANDARD;

D O I：

10.1366/0003702934415183

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

Direct analysis of the organic phase of an emulsion polymerization is described. Quantification uses the bending mode peak of water, which makes up the bulk of the reaction medium, as an internal standard. Although demonstrated with methyl methacrylate, the process is generally applicable to emulsion polymerizations. It does not require the introduction of an extraneous internal standard component into the reaction mixture.

引用

页码：928 / 932

页数：5