REACTIONS OF BIS[1,2-BIS(DIALKYLPHOSPHINO)ETHANE]-(DIHYDROGEN)HYDRIDOIRON(1+) WITH ALKYNES

被引：42

作者：

HUGHES, DL

JIMENEZTENORIO, M

LEIGH, GJ

ROWLEY, AT

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 21期

关键词：

D O I：

10.1039/dt9930003151

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds [FeH(H2)(dmpe)2]BPh4 and [FeH(H2)(depe)2]BPh4 (dmpe=Me2PCH2CH2PMe2 and depe = Et2PCH2CH2PEt2) reacted with terminal alkynes R'CCH (R = Me, Pr(i) or Ph) to yield a variety of structures, apparently formed in sequence, bis(alkynyl), alkynyl(vinylidene) and substituted butenynyl complexes of iron(II), which also contain bis(diphosphines). The structures of trans-[Fe(CCMe)(CCHMe)(dmpe)2]BF4, trans-[Fe(CCPr(i))(CCHPr(i))(dmpe)2]BF4, [Fe(MeCCCCHMe)-(depe)2]BPh4 and [Fe(PhCCCCPh)(dmpe)2]BPh4 have been determined and the interconversions of the complexes are discussed.

引用

收藏

页码：3151 / 3162

页数：12

相关论文

共 34 条

[1] REACTIONS OF MOLECULAR-HYDROGEN COMPLEXES [RUH(ETA-2-H2)P4]BF4 WITH ALKYNES - PREPARATION AND CRYSTAL-STRUCTURE OF THE [RU(ETA-3-(PARA-TOLYL)C3CH(PARA-TOLYL))(PHP(OET)2)4]BPH4 DERIVATIVE [J].

ALBERTIN, G ;

AMENDOLA, P ;

ANTONIUTTI, S ;

IANELLI, S ;

PELIZZI, G ;

BORDIGNON, E .

ORGANOMETALLICS, 1991, 10 (08) :2876-2883

[2] REACTIVITY OF IRON(II) NONCLASSICAL HYDRIDES WITH ALKYNES [J].

ALBERTIN, G ;

ANTONIUTTI, S ;

DELMINISTRO, E ;

BORDIGNON, E .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (22) :3203-3208

[3] POLYAZOLYL CHELATE CHEMISTRY .3. (SIGMA-ORGANYL)(TRIS(PYRAZOL-1-YL)BORATO)RUTHENIUM COMPLEXES [J].

ALCOCK, NW ;

HILL, AF ;

MELLING, RP .

ORGANOMETALLICS, 1991, 10 (11) :3898-3903

[4] DINITROGEN COMPLEXES OF TUNGSTEN WITH BULKY PHOSPHINE CO-LIGANDS - PREPARATION AND CRYSTAL-STRUCTURES OF [(W(N2)2(PET2PH)3)2(MU-N2)], TRANS-[W(N2)2(PET2PH)4].C4H8O, AND "[W(ETA-6-C6H5PPRN2)(N-2)(PPRN2PH)2] AND THEIR REACTIONS TO GIVE HYDRAZINE OR AMMONIA [J].

ANDERSON, SN ;

RICHARDS, RL ;

HUGHES, DL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (02) :245-252

[5]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]

[6] FORMATION OF MOLECULAR-HYDROGEN COMPLEXES OF IRON BY THE REVERSIBLE PROTONATION OF IRON DIHYDRIDES WITH ALCOHOLS [J].

BAKER, MV ;

FIELD, LD ;

YOUNG, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (08) :546-548

[7] MOSSBAUER AND PREPARATIVE STUDIES OF SOME IRON(II) COMPLEXES OF DIPHOSPHINES [J].

BARCLAY, JE ;

LEIGH, GJ ;

HOULTON, A ;

SILVER, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11) :2865-2870

[8]

BASALLOTTE MG, UNPUB

[9] A HOMOGENEOUS IRON(II) SYSTEM CAPABLE OF SELECTIVELY CATALYZING THE REDUCTION OF TERMINAL ALKYNES TO ALKENES AND BUTA-1,3-DIENES [J].

BIANCHINI, C ;

MELI, A ;

PERUZZINI, M ;

VIZZA, F ;

ZANOBINI, F ;

FREDIANI, P .

ORGANOMETALLICS, 1989, 8 (08) :2080-2082

[10] A DECEPTIVELY SIMPLE CASE OF SELECTIVE HYDROGENATION OF PHENYLACETYLENE TO STYRENE CATALYZED BY A CIS-HYDRIDO(MU-2-DIHYDROGEN)RUTHENIUM(II) COMPLEX [J].

BIANCHINI, C ;

BOHANNA, C ;

ESTERUELAS, MA ;

FREDIANI, P ;

MELI, A ;

ORO, LA ;

PERUZZINI, M .

ORGANOMETALLICS, 1992, 11 (11) :3837-3844

← 1 2 3 4 →