NITROGEN-CONTAINING CARBOHYDRATE DERIVATIVES .19. CONFORMATION AND PROTON SPIN-COUPLING IN METHYL AMINO-4,6-O-BENZYLIDENE-DEOXY-ALPHA-D-GLYCOSIDES

被引:12
作者
BARLOW, CB
BISHOP, EO
CAREY, PR
GUTHRIE, RD
机构
[1] School of Molecular Sciences, University of Sussex, Brighton
关键词
D O I
10.1016/S0008-6215(00)82892-X
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A detailed study of the proton magnetic resonance spectra of the complete series of methyl 2(or 3)-amino-4,6-O-benzylidene-2(or 3)-deoxy-α-D-glycosides has shown that they exist in the expected chair conformation in chloroform. Complete analyses of the ring-proton spectra were carried out in several cases. Coupling constants over two to five bonds are discussed. © 1969.
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页码:99 / &
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