ELECTROCHEMISTRY OF CYANOCOPPER THIOMOLYBDATES AND THIOTUNGSTATES - REDOX-BASED INTERCONVERSION OF SPECIES

被引：9

作者：

KONY, M

BOND, AM

WEDD, AG

机构：

[1] LA TROBE UNIV,DEPT CHEM,BUNDOORA,VIC 3083,AUSTRALIA

[2] DEAKIN UNIV,DEPT CHEM & ANALYT SCI,GEELONG,VIC 3217,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 22期

关键词：

D O I：

10.1021/ic00347a038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[MoS4]2and its 1:1 and 1:2 CuCN adducts [(CN)CuS2MoS2]2−and [(CN)CuS2MoS2Cu(CN)]2−each exhibit electrochemically reversible one-electron reductions in MeCN at fast scan rates (>500 mV s−1). At lower scan rates, the reduced adduct species are unstable to dissociation of CuCN, leading to interconversion of the three anions. The tungsten analogues show similar properties. © 1990, American Chemical Society. All rights reserved.

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页码：4521 / 4525

页数：5

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