NEW TITANIUM BORON COMPLEXES WITH A PLANAR TETRACOORDINATE CARBON OR A PLANAR TRICOORDINATE PHOSPHORUS CENTER

被引：33

作者：

BINGER, P ^{[1
]}

SANDMEYER, F ^{[1
]}

KRUGER, C ^{[1
]}

KUHNIGK, J ^{[1
]}

GODDARD, R ^{[1
]}

ERKER, G ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1002/anie.199401971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel coordination geometry of phosphorus is achieved in a simple way by the reaction of the (η2‐tert‐butylphosphaalkyne)titanocene 1 with tetraethyldiborane [Eq. (a)]. The resulting dinuclear complex 2 contains a planar tricoordinate phosphorus atom whose lone pair of electrons is not involved in bonding. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：197 / 198

页数：2

共 22 条

[1] SYNTHESIS AND STRUCTURE OF A BRIDGING PHOSPHA-ALKENYL COMPLEX
ARIF, AM
COWLEY, AH
QUASHIE, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (07) : 428 - 429
[2] ETA-2-TERT-BUTYLPHOSPHAACETYLENE COMPLEXES OF TITANOCENE AND ZIRCONOCENE
BINGER, P
BIEDENBACH, B
HERRMANN, AT
LANGHAUSER, F
BETZ, P
GODDARD, R
KRUGER, C
[J]. CHEMISCHE BERICHTE, 1990, 123 (08) : 1617 - 1623
[3] Brown H. C., 1962, HYDROBORATION
[4] (ARYNE)METALLOCENE-DERIVED AND (ALKYNE)METALLOCENE-DERIVED DIMETALLIC ZIRCONIUM ALUMINUM COMPLEXES CONTAINING PLANAR-TETRACOORDINATE CARBON
ERKER, G
ALBRECHT, M
KRUGER, C
WERNER, S
BINGER, P
LANGHAUSER, F
[J]. ORGANOMETALLICS, 1992, 11 (11) : 3517 - 3525
[5] Erker G, 1992, COMMENTS INORG CHEM, V13, P111, DOI DOI 10.1080/02603599208048461
[6] ERKER G, 1992, NACHR CHEM TECH LAB, V40, P1099
[7] AN ABINITIO MO STUDY ON STABILIZING INTERACTIONS IN DINUCLEAR ZR/AL COMPLEXES WITH A PLANAR TETRACOORDINATE CARBON CENTER
GLEITER, R
HYLAKRYSPIN, I
NIU, SQ
ERKER, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05): : 754 - 756
[8] Gleiter R., 1993, ANGEW CHEM, V105, P753
[9] SYNTHESIS OF A PHOSPHAVINYL COMPLEX VIA SHIFT OF A PENTAMETHYLCYCLOPENTADIENYL FROM PHOSPHORUS TO IRON
GUDAT, D
NIECKE, E
ARIF, AM
COWLEY, AH
QUASHIE, S
[J]. ORGANOMETALLICS, 1986, 5 (03) : 593 - 595
[10] SYNTHESIS AND CHARACTERIZATION OF LONG-CHAIN ALKYLIDENE-BRIDGED HETERO BIMETALLIC COMPLEXES
HARTNER, FW
SCHWARTZ, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (16) : 4979 - 4981

← 1 2 3 →