SYNTHESIS OF ARENE TI AND ZR COMPLEXES AND THEIR REACTIVITY TOWARDS AIR - CRYSTAL-STRUCTURE OF [(C(6)H(3)ME(3))(2)ZR(ALCL4)](AL2CL7) AND TICL3(OPH)

被引：9

作者：

TROYANOV, S

PISAREVSKY, A

STRUCHKOV, YT

机构：

[1] Chemistry Department, Moscow State University

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 494卷 / 1-2期

关键词：

ZIRCONIUM; TITANIUM; ALUMINUM; ARENE; OXIDATION;

D O I：

10.1016/0022-328X(95)05438-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [(C(6)H(3)Me(3))(2)Zr(mu-Cl)(2)AlCl2](Al2Cl7) has been prepared by reductive Friedel-Crafts synthesis. its structure confirms remarkable differences in chemistry of arene complexes of Ti(II) and Zr(II). The crystalline complex TiCl3(OPh) was formed by slow oxidation of (C6H6)TiAl2Cl8 in air, whereas partial oxidation of Zr arene complexes gave the oxohalogenoaluminates containing cationic arene Zr(II) species.

引用

页码：C4 / C7

页数：4

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