COPPER-ASSISTED DISPLACEMENT REACTION OF NONACTIVATED IODOARENES WITH ARENESULFINATES - CONVENIENT ALTERNATIVE SYNTHESIS OF UNSYMMETRICAL DIARYL SULFONES

被引：96

作者：

SUZUKI, H

ABE, H

机构：

[1] Department of Chemistry, Faculty of Science, Kyoto University, Sakyo-ku, Kyoto

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 35期

关键词：

D O I：

10.1016/0040-4039(95)01095-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of copper(I) iodide in hot N,N-dimethylformamide (DMF), a variety of functionalized iodoarenes undergo nucleophilic displacement reaction with sodium arenesulfinates to give the corresponding unsymmetrical diaryl sulfones in moderate to good yields.

引用

页码：6239 / 6242

页数：4

共 18 条

[1]

BAARSCHERS WH, 1925, J AM CHEM SOC, V47, P2047

[2] CONTROL OF CHEMOSELECTIVITY AND STEREOSELECTIVITY IN THE REACTIONS OF ORGANOCUPRATES WITH ALPHA-OXOKETENE DITHIOACETALS [J].