Origin of the stability of aromatic hydrocarbon dimers

被引：6

作者：

Chandra, A. K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 76, Maharashtra, India

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 5卷 / 04期

关键词：

D O I：

10.1016/0009-2614(70)85012-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is shown using simple perturbation theory that the intermolecular pi-electron interaction leads to stabilisation of aromatic hydrocarbon dimers of certain tilted configuration with respect to two infinitely isolated monomers. The condition of stability of these dimers is the occurrence of lowlying pi-electronic excited states in monomers.

引用

页码：229 / 231

页数：3

共 13 条

[1] ENERGY OF EXCIMER LUMINESCENCE .2. CONFIGURATION INTERACTION BETWEEN MOLECULAR EXCITON STATES AND CHARGE RESONANCE STATES
AZUMI, T
ARMSTRONG, AT
MCGLYNN, SP
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (12) : 3839 - +
[2] MOLECULAR CHARGE DISTRIBUTIONS AND CHEMICAL BINDING
BADER, RFW
HENNEKER, WH
CADE, PE
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (09) : 3341 - &
[3] CRYSTAL AND MOLECULAR STRUCTURE OF PENTACENE
CAMPBELL, RB
TROTTER, J
ROBERTSON, JM
[J]. ACTA CRYSTALLOGRAPHICA, 1961, 14 (07): : 705 - &
[4] CHANDRA A, UNPUB
[5] SEMIEMPIRICAL THEORY OF EXCIMER LUMINESCENCE .2. COMPARISON WITH PREVIOUS THEORIES AND CONSIDERATION OF TRANSITION PROBABILITY AND STABILITY OF EXCIMER TRIPLET STATE
CHANDRA, AK
LIM, EC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (11) : 5066 - &
[6] SEMIEMPIRICAL THEORY OF EXCIMER LUMINESCENCE
CHANDRA, AK
LIM, EC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (06) : 2589 - &
[7] CHANDRA AK, 1968, CAN J CHEM, V46, P953
[8] ABSORPTION AND EMISSION SPECTRA OF ANTHRACENE DIMERS
CHANDROSS, EA
FERGUSON, J
MCRAE, EG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (10) : 3546 - +
[9] VIBRONIC COUPLING .1. MATHEMATICAL TREATMENT FOR 2 ELECTRONIC STATES
FULTON, RL
GOUTERMAN, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1961, 35 (03) : 1059 - &
[10] VIBRONIC COUPLING .2. SPECTRA OF DIMERS
FULTON, RL
GOUTERMAN, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (08) : 2280 - &

← 1 2 →