A FACILE SYNTHESIS OF 4-ALKOXYMETHYLPHENOLS BY A COPPER(II)-ACETOXIME CATALYST/O2 SYSTEM

被引：16

作者：

SHIMIZU, M

WATANABE, Y

ORITA, H

HAYAKAWA, T

TAKEHIRA, K

机构：

[1] National Chemical Laboratory for Industry, Tsukuba Research Center, Tsukuba, Ibaraki

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 18期

关键词：

OXYGENATION; PHENOL; COPPER(II); CATALYST; OXIME;

D O I：

10.1016/S0040-4039(00)78906-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

4-Alkoxymethyl-2,6-dimethylphenols were synthesized from 2,4,6-trimethylphenol in good yields by a copper(II) chloride-acetoxime catalyst/molecular oxygen system in alcohols at ambient temperature. The oxidation of the other p-methylsubstituted phenols were also examined.

引用

页码：2053 / 2056

页数：4

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ADLER E, 1975, ACTA CHEM SCAND B, V29, P909, DOI 10.3891/acta.chem.scand.29b-0909

[2]

BECKER HD, 1968, J ORG CHEM, V33, P2516

[3]

BOUQUET M, 1984, CR ACAD SCI II, V299, P1389

[4] MIGRATIONS IN OXIDATIONS OF MESIDINE [J].