SYNTHESIS OF THE THERMALLY UNSTABLE ARACHNO CLUSTER FE2(CO)6(MU-3-S)2NI(1,5-COD) AND OBSERVATION OF FACILE DECOMPOSITION TO FENIS

被引：11

作者：

DON, MJ ^{[1
]}

RICHMOND, MG ^{[1
]}

机构：

[1] UNIV N TEXAS,CTR ORGANOMET RES & EDUC,DEPT CHEM,DENTON,TX 76203

来源：

INORGANICA CHIMICA ACTA | 1993年 / 210卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)82832-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Fe2(CO)6(mu2-S)2 and (1,5-COD)2Ni gives the arachno cluster Fe2(CO)6(mu3-S)2Ni(1,5-COD) at - 78-degrees-C in toluene. This new cluster is stable at low temperature and has been characterized by low-temperature IR spectroscopy. Cluster decomposition occurs upon warming to yield amorphous FeNiS, which has been characterized by energy-dispersive X-ray analysis (EDAX).

引用

页码：129 / 130

页数：2

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