ASYMMETRIC CONJUGATE ADDITION OF ORGANOMAGNESIUM CUPRATES CONTROLLED BY A STOICHIOMETRIC AMOUNT OF CHIRAL PHOSPHINE

被引：35

作者：

KANAI, M ^{[1
]}

TOMIOKA, K ^{[1
]}

机构：

[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

关键词：

D O I：

10.1016/0040-4039(95)00758-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A dramatic reversal in the enantiofacial differentiation was observed in a chiral phosphine mediated organocuprate addition to cycloalkenone, providing S- and R-product in up to 98% ee by using magnesium- and lithium cuprate, respectively.

引用

页码：4273 / 4274

页数：2

共 8 条

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