PRESSURE AND TEMPERATURE-DEPENDENCE OF THE PROPAGATION RATE COEFFICIENT IN FREE-RADICAL POLYMERIZATION OF BUTYL METHACRYLATE

被引:19
作者
BERGERT, U [1 ]
BUBACK, M [1 ]
HEYNE, J [1 ]
机构
[1] ROHM GMBH CHEM FABR,D-64293 DARMSTADT,GERMANY
关键词
D O I
10.1002/marc.1995.030160408
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The propagation rate coefficient in free-radical bulk polymerization of butyl methacrylate has been studied at temperatures between - 10 degrees C and 60 degrees C up to a maximum pressure of 2000 bar. The data were obtained by means of the PLP-GPC technique which combines pulsed-laser polymerization with product analysis by gel-permeation chromatography.
引用
收藏
页码:275 / 281
页数:7
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