COMPLEX DEFECTS IN COO

被引:18
作者
HED, AZ
机构
[1] Battette Memorial Institute, Columbus
关键词
D O I
10.1063/1.1671487
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The isobaric electrical conductivity of CoO has been measured in the range 850°-1200°C, at oxygen pressures between 10-0.88-10 -2.88 atm. From the slopes of the isobars it is concluded that the enthalpy of formation of some of the defects is negative, and these defects are therefore complex. It is suggested that the dominant complex defect consists of an interstitial Co cation and two Co vacancies.
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页码:2935 / &
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