RADICAL POLYMERIZATIONS INVOLVING ESTERS OF VINYL ALCOHOL .I. REACTIVITIES OF MONOMERS TOWARDS BENZOYLOXY RADICAL

被引：3

作者：

BEVINGTON, JC

JOHNSON, M

机构：

[1] Department of Chemistry, The University, Lancaster

来源：

EUROPEAN POLYMER JOURNAL | 1968年 / 4卷 / 03期

关键词：

D O I：

10.1016/0014-3057(68)90025-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

14C-benzoyl peroxide has been used at 60° to initiate polymerizations of vinyl formate, propionate, butyrate, benzoate and phenyl acetate at various concentrations in benzene. The relative numbers of benzoyloxy and phenyl end-groups in the various polymers have been determined; these numbers have been used to deduce the relative reactivities of the monomers towards the benzoyloxy radical. © 1968.

引用

页码：373 / +

页数：1

共 6 条

[1] RELATIVE REACTIVITIES IN VINYL COPOLYMERIZATION [J].

ALFREY, T ;

PRICE, CC .

JOURNAL OF POLYMER SCIENCE, 1947, 2 (01) :101-106

[2] A TRACER STUDY OF THE BENZOYLOXY RADICAL [J].

BARSON, CA ;

BEVINGTON, JC .

TETRAHEDRON, 1958, 4 (1-2) :147-156

[3] THE REACTIVITIES OF MONOMERS TOWARDS THE BENZOYLOXY RADICAL [J].

BARSON, CA ;

BEVINGTON, JC ;

EAVES, DE .

TRANSACTIONS OF THE FARADAY SOCIETY, 1958, 54 (11) :1678-1683

[4]

Bevington J. C., 1965, EUR POLYM J, V1, P235

[5] THE NATURE OF THE INITIATION REACTION IN THE POLYMERIZATION OF STYRENE SENSITIZED BY BENZOYL PEROXIDE [J].

BEVINGTON, JC .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1957, 239 (1218) :420-432

[6]

BEVINGTON JC, 1961, RADICAL POLYMERIZATI, P41

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