DENSITY, CONDUCTANCE, TRANSFERENCE NUMBERS, AND DIFFUSION MEASUREMENTS IN CONCENTRATED-SOLUTIONS OF NICKEL CHLORIDE AT 25-DEGREES-C

被引：73

作者：

STOKES, RH

PHANG, S

MILLS, R

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH PHYS SCI,DIFFUS RES UNIT,CANBERRA 2600,ACT,AUSTRALIA

[2] UNIV NEW ENGLAND,DEPT PHYS & INORGAN CHEM,ARMIDALE 2351,NEW S WALES,AUSTRALIA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1979年 / 8卷 / 07期

关键词：

aqueous nickel chloride; concentrated solutions; conductance; density; Hittorf; moving boundary; mutual diffusion; tracer diffusion; Transference number;

D O I：

10.1007/BF00655205

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Hittorf technique for measuring transference numbers has been modified to produce precise data in concentrated aqueous electrolyte solutions. Density, molar conductance, transference number, tracer-diffusion, and mutual diffusion data are reported for aqueous NiCl2 solutions up to 4 M concentration at 25°C. © 1979 Plenum Publishing Corporation.

引用

页码：489 / 500

页数：12

共 23 条

[1] [Anonymous], 1928, INT CRITICAL TABLES, VIII
[2] VOLUME CORRECTION FOR DIRECT AND INDIRECT MOVING BOUNDARY TRANSFERENCE MEASUREMENTS
GWYTHER, JR
SPIRO, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 : 1410 - 1418
[3] HAASE R, 1967, Z NATURFORSCH PT A, VA 22, P1761
[4] The transport numbers of zinc chloride from EMF measurements.
Harris, AC
Parton, HN
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1940, 36 : 1139 - 1141
[5] EFFECT OF STRUCTURE ON SELF-DIFFUSION IN CONCENTRATED ELECTROLYTES - RELATIONSHIP BETWEEN WATER AND IONIC SELF-DIFFUSION COEFFICIENTS FOR STRUCTURE-FORMING SALTS
HARRIS, KR
HERTZ, HG
MILLS, R
[J]. JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1978, 75 (04) : 391 - 396
[6] A new method for the determination of transport numbers. Part I. Theory of the method.
Hartley, GS
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1934, 30 : 0648 - 0652
[7] VELOCITY CORRELATIONS IN AQUEOUS-ELECTROLYTE SOLUTIONS FROM DIFFUSION, CONDUCTANCE, AND TRANSFERENCE DATA .2. APPLICATIONS TO CONCENTRATED-SOLUTIONS OF 1-1 ELECTROLYTES
HERTZ, HG
HARRIS, KR
MILLS, R
WOOLF, LA
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1977, 81 (07): : 664 - 670
[8] VELOCITY CORRELATIONS IN AQUEOUS-ELECTROLYTE SOLUTIONS FROM DIFFUSION, CONDUCTANCE, AND TRANSFERENCE DATA - APPLICATIONS TO CONCENTRATED-SOLUTIONS OF 1-2 ELECTROLYTES
HERTZ, HG
MILLS, R
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (08) : 952 - 959
[9] VELOCITY CORRELATIONS IN AQUEOUS-ELECTROLYTE SOLUTIONS FROM DIFFUSION, CONDUCTANCE, AND TRANSFERENCE DATA .1. THEORY
HERTZ, HG
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1977, 81 (07): : 656 - 664
[10] ION DISTRIBUTION AND LONG-RANGE ORDER IN CONCENTRATED ELECTROLYTE SOLUTIONS
HOWE, RA
HOWELLS, WS
ENDERBY, JE
[J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1974, 7 (07): : L111 - L114

← 1 2 3 →