STEREOCONTROL USING SILICON - A SYNTHESIS OF METHYL (+)-NONACTATE

被引：22

作者：

AHMAR, M

DUYCK, C

FLEMING, I

机构：

[1] Department of Chemistry, Cambridge CB2 1EW, Lensfield Road

来源：

PURE AND APPLIED CHEMISTRY | 1994年 / 66卷 / 10-11期

关键词：

D O I：

10.1351/pac199466102049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The phenyldimethylsilyl group is separately introduced (10 --> 11 13 --> 14) onto a carbon chain with absolute stereocontrol, controlling the relative stereochemistry of 1,4-related centres; the silyl groups are independently used to control the relative stereochemistry of 1,3- and 1,2-related centres (11 --> 12 and 15 --> 16) in a synthesis of methyl (+)-nonactate 7.

引用

页码：2049 / 2052

页数：4

共 32 条

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