MATRIX INFRARED STUDIES OF THE HCN+O-3 AND HCN+O SYSTEMS

被引：30

作者：

MIELKE, Z ^{[1
]}

ANDREWS, L ^{[1
]}

机构：

[1] UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 09期

关键词：

D O I：

10.1021/j100372a030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Codeposition of argon-diluted samples of O3 and HCN produced a unique 1:1 O3-HCN complex where the C2v, symmetry of O3 is retained and HCN appears to form weak hydrogen bonding interactions with both terminal atoms of O3. Complexes with isotopic substitution at all atomic positions were studied. Photolysis of Ar/HCN/O3 samples with the full mercury arc produced the O-HCN hydrogen-bonded complex and HNCO as primary products and (HNCO)2 as a secondary product. © 1990 American Chemical Society.

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页码：3519 / 3525

页数：7

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