THE VOLUME PROFILE FOR A CHELETROPIC REACTION

被引：11

作者：

ISAACS, NS ^{[1
]}

LAILA, A ^{[1
]}

机构：

[1] UNIV BIRZEIT,DEPT CHEM,BIRZEIT,ISRAEL

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1994年 / 7卷 / 04期

关键词：

D O I：

10.1002/poc.610070403

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The volumes of activation and of reaction were measured for the reaction between sulphur dioxide and 2,3-dimethylbuta-1,3-diene to form 3,4-dimethylsulpholene. Values of DELTAV and DELTAV* are -33 and -35 cm3 mol-1, respectively in accordance with a concerted reaction having a very product-like transition state.

引用

页码：178 / 180

页数：3

共 11 条

[1] HETERO-DIELS-ALDER ADDITION OF SULFUR-DIOXIDE TO 1,3-DIENES - SUPRAFACIALITY, REGIOSELECTIVITY, AND STEREOSELECTIVITY [J].