C-NITROSO COMPOUNDS .7. AN ESR STUDY OF ALKYLNITROXIDES

被引：41

作者：

WAJER, TAJ

MACKOR, A

DEBOER, TJ

机构：

[1] Laboratory for Organic Chemistry, University of Amsterdam, Amsterdam

来源：

TETRAHEDRON | 1969年 / 25卷 / 01期

关键词：

D O I：

10.1016/S0040-4020(01)99469-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is demonstrated that alkylnitroxides can be generated from nitrosoalkanes by thermal reduction with hydroxylamines or by photoreduction with thiophenol. The solvent dependence of the ratio of the nitrogen and hydrogen splitting constants in t-butylnitroxide is explained on the basis of mesomeric contributions to the structure of the radical. © 1969.

引用

收藏

页码：175 / &

相关论文

共 24 条

[1] PARAMAGNETIC RESONANCE OF ALKYL NITROXIDES [J].

ADAMS, JQ ;

NICKSIC, SW ;

THOMAS, JR .

JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (02) :654-+

[2] PARAMAGNETIC RESONANCE OF FREE RADICAL INTERMEDIATES IN REACTION OF OH WITH OXIMES [J].

ADAMS, JQ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (24) :6022-&

[3] PHOTODISSOCIATION OF NITROSO DIMERS [J].

BLUHM, AL ;

WEINSTEIN, J .

NATURE, 1967, 215 (5109) :1478-+

[4]

CARRINGTON A, 1967, INTRO MAGNETIC RESON, P80

[5] SOLVENT EFFECTS IN ELECTRON SPIN RESONANCE SPECTRA [J].

GENDELL, J ;

FRAENKEL, GK ;

FREED, JH .

JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (12) :2832-&

[6] REDUCTION OF SOME CONJUGATED AZOMETHINE SYSTEMS BY ARYL THIOLS [J].

GILMAN, H ;

TOWLE, JL ;

INGHAM, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (11) :2920-2923

[7]

GULBARAN E, 1964, SUOM KEMISTIL, VB 37, P229

[8] ELECTRON SPIN RESONANCE SPECTRA OF SOME HYDROXYLAMINE FREE RADICALS [J].

GUTCH, CJW ;

WATERS, WA .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JAN) :751-&

[9] ELECTRON SPIN RESONANCE OF SOME DIALKYL NITROXIDES [J].

HUDSON, A ;

HUSSAIN, HA .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1967, (12) :1299-&

[10] THEORETICAL INTERPRETATION OF CARBON-13 HYPERFINE INTERACTIONS IN ELECTRON SPIN RESONANCE SPECTRA [J].

KARPLUS, M ;

FRAENKEL, GK .

JOURNAL OF CHEMICAL PHYSICS, 1961, 35 (04) :1312-&