DIRECT FLUORINATION OF POLYETHYLENE POWDER

被引：5

作者：

OKADA, M

MAKUUCHI, K

机构：

[1] Takasaki Radiation Chemistry Research Establishment, Japan Atomic Energy Research Institute

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/i360031a026

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

To improve the physical properties of polyethylene, the method of fluorinating polyethylene powder was investigated. Batch reaction vessels were used. To prevent a fiery, intense reaction, the following are effective: use of fluorine at low pressures; use of helium or nitrogen as diluent for fluorine; choice of reaction-vessel shape to minimize fluorine velocity on a powder sample when fluorine is supplied; keeping a polyethylene sample in vacuum for a sufficient time before fluorination starts; and raising the reaction temperature to about 90° C. The weight increase of polyethylene during fluorination is proportional to the 0.28th power of time. © 1969, American Chemical Society. All rights reserved.

引用

页码：334 / &