CRYSTAL AND MOLECULAR-STRUCTURE OF THE TETRAMERIC CLUSTER CADMIUM COMPLEX FORMED FROM 1,4,7,10-TETRAOXA-13-AZACYCLOPENTADECANE-13-ACETIC ACID

被引：9

作者：

BYRIEL, KA

GAHAN, LR

KENNARD, CHL

LATTEN, JL

HEALY, PC

机构：

[1] UNIV QUEENSLAND,DEPT CHEM,BRISBANE,QLD 4072,AUSTRALIA

[2] GRIFFITH UNIV,SCH SCI,NATHAN,QLD 4111,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1993年 / 46卷 / 05期

关键词：

D O I：

10.1071/CH9930713

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of cadmium carbonate with 1,4,7,10-tetraoxa-13-azacyclopentadecane-13-acetic acid (HL4) in warm aqueous solution results in the isolation of crystals of the tetrameric cluster [Cd4(L4)4] [CdCl4]2.3H2O, an ordered assembly of acetate-bridged macrocyclic species. The crystals are triclinic, space group P1BAR with a 15.67(3), b 16.90(2), c 17.92(3) angstrom, alpha 101.41(4), beta 115.57(7), gamma 102.23(8)-degrees. R was 0.045 for 7191 [I > 2.5sigma(I)] reflections.

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页码：713 / 719

页数：7

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