CHEMICAL-COMPOSITION OF HUMIC ACIDS - A COMPARISON WITH PRECURSOR LIGHT FRACTION LITTER FROM DIFFERENT VEGETATIONS USING SPECTROSCOPIC TECHNIQUES

被引:22
作者
AMALFITANO, C
QUEZADA, RA
WILSON, MA
HANNA, JV
机构
[1] CSIRO, DIV PETR RESOURCES, POB 136, N RYDE, NSW 2113, AUSTRALIA
[2] CSIRO, DIV COAL & ENERGY TECHNOL, N RYDE, NSW 2113, AUSTRALIA
[3] UNIV NAPOLI FEDERICO 2, DIPARTIMENTO SCI CHIM AGR, I-80055 PORTICI, ITALY
关键词
D O I
10.1097/00010694-199506000-00004
中图分类号
S15 [土壤学];
学科分类号
0903 ; 090301 ;
摘要
Humic acids from a range of Italian soils and the residual suspended organic material (light fraction litter) associated with them have been studied by pyrolysis gas chromatography mass spectrometry, solid state nuclear magnetic resonance spectroscopy, and infra-red spectroscopy. Although the major vegetation types on the soils differ considerably, spectra of humic acids from soils with different major vegetation types were similar. Because no relationship between humic acid structure and major vegetation type was observed, gross assumptions about humic acid structure should not be drawn from a knowledge of macro-vegetation types on soils. Light fraction litter in the soils from minor vegetation may be more significant in affecting the eventual structure of the humic acids.
引用
收藏
页码:391 / 401
页数:11
相关论文
共 31 条
[1]  
Baldock J.A., Oades J.M., Waters A.G., Peng X., Vassallo A.M., Wilson M.A., Aspects of the chemical structure of soil organic materials as revealed by solid-state<sup>13</sup>C NMR spectroscopy, Biogeochemistry, 16, pp. 1-12, (1992)
[2]  
Black C.A., Methods of Soil Analysis, Part 2. Chemical and Microbiological Properties, (1965)
[3]  
Hatcher P.G., Chemical structural studies of natural lignin by dipolar dephasing solid-state<sup>13</sup>C nuclear magnetic resonance, Org. Geochem., 11, pp. 31-39, (1987)
[4]  
Hatcher P.G., Dipolar-dephasing<sup>13</sup>C NMR studies of decomposed wood and coalified xylem tissue: Evidence for chemical structural changes associated with defunctionalisation of lignin structural units during coalification, Energy and Fuels, 2, pp. 40-58, (1988)
[5]  
Hatcher P.G., Schnitzer M., Dennis L.W., Maciel G.E., Aromaticity of humic substances in soils, Soil Sci. Soc. Am. J., 45, pp. 1089-1094, (1981)
[6]  
Hatcher P.G., Spiker E.C., Selective degradation of plant biomolecules, Humic Substances and Their Role in the Environment, pp. 59-74, (1988)
[7]  
Hempfling R., Ziegler F., Zech W., Schulten H.R., Litter decomposition and humification in acidic forest soils studied by chemical degradation, IR and NMR spectrometry and pyrolysis field ionisation mass spectrometry, Z. Planzenernahr. Bodenk., 150, pp. 179-186, (1978)
[8]  
Hempfling R., Schulten H.-R., Selective preservation of biomolecules during humification of forest litter studied by pyrolysis-fleld ionization mass spectrometry, Sci. Total Environ., 81-82, pp. 31-40, (1989)
[9]  
Hempfling R., Schulten H.-R., Chemical characterization of the organic matter in forest soils by Curie point pyrolysis-GC/MS and pyrolysis-field ionization mass spectrometry, Org. Geochem., 15, pp. 131-145, (1990)
[10]  
Outline of extraction procedures, Proc. 1st International Humic Substances Society Conference Estes Park, (1983)