VISUAL PIGMENTS .10. SPECTROSCOPY AND PHOTOPHYSICAL DYNAMICS OF RETINOL AND RETINYL ETHER

被引：30

作者：

CHIHARA, K

TAKEMURA, T

YAMAOKA, T

YAMAMOTO, N

SCHAFFER, A

BECKER, RS

机构：

[1] Department of Chemistry, University of Houston, Houston, Texas

来源：

PHOTOCHEMISTRY AND PHOTOBIOLOGY | 1979年 / 29卷 / 05期

关键词：

D O I：

10.1111/j.1751-1097.1979.tb07804.x

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Abstract— The absorption and emission spectra, lifetimes and quantum yields of all‐trans retinol have been examined as a function of solvent and temperature. In addition, the spectroscopy of retinyl ether and 2 other polyene alcohols have been determined. Based on the results obtained, we conclude that the singlet excited state of retinol and retinyl cther is of a forbidden character and of the type loosely called 1A‐g. Retinol forms a dimer in an alkane solvent when cooling from 298 to 77 K. A general structure for the dimer is proposed. Copyright © 1979, Wiley Blackwell. All rights reserved

引用

页码：1001 / 1008

页数：8

共 13 条

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