NORMAL-OCTANE LIQUID-PHASE OXIDATION CATALYZED BY COBALT SALTS - OVERALL KINETIC AND PRODUCT DISTRIBUTION

被引：3

作者：

GARCIAOCHOA, F

ROMERO, A

QUEROL, J

机构：

[1] Dpto. Ingenieria Quimica, Facultad CC, Quimicas, Madrid

来源：

CHEMICAL ENGINEERING JOURNAL AND THE BIOCHEMICAL ENGINEERING JOURNAL | 1990年 / 43卷 / 01期

关键词：

D O I：

10.1016/0300-9467(90)80042-B

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

n-Octane liquid-phase oxidation with oxygen-nitrogen mixtures homogeneously catalyzed by cobalt palmitate has been studied. The temperature (135 °C, 140 °C and 145 °C), the oxygen partial pressure (0.1 atm, 0.2 atm and 0.4 atm) and the catalyst concentration (1 ppm, 10 ppm and 100 ppm of Co) have been varied. An overall kinetic equation for the disappearance of hydrocarbon was determined and the influence of the experimental variables on the product distribution was analyzed. The ketone and alcohol isomers and acid distributions are also discussed. © 1990.

引用

页码：33 / 40

页数：8

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