PARTIALLY DIFFUSION-CONTROLLED RECOMBINATION

被引：283

作者：

SANO, H ^{[1
]}

TACHIYA, M ^{[1
]}

机构：

[1] NATL CHEM LAB IND, DIV BAS RES, SHIBUYA KU, TOKYO 151, JAPAN

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 03期

关键词：

D O I：

10.1063/1.438427

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We extend Tachiya's method for treating totally diffusion-controlled recombination of a pair of particles to partially diffusion-controlled recombination. The differential equation satisfied by the survival probability of the pair is derived, and solved for several cases of practical interest. Recent experiments on the solvated electron yield in irradiated liquid ammonia are analyzed by use of the present theory. It is confirmed that the rather high yield of solvated electrons in liquid ammonia is due to the slowness of the recombination reaction es-+NH4+. © 1979 American Institute of Physics.

引用

页码：1276 / 1282

页数：7

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