DIELS-ALDER REACTIONS OF TRANS-1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE

被引：202

作者：

DANISHEFSKY, S

KITAHARA, T

YAN, CF

MORRIS, J

机构：

[1] Contribution from the Department of Chemistry, University of Pittsburgh, 15260, Pittsburgh, Pennsylvania

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 23期

关键词：

D O I：

10.1021/ja00517a036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enol silylation of trans-4-methoxybut-3-en-2-one affords trans-1-methoxy-3-trimethylsilyloxy-1,3-butadiene (1). This compound has been demonstrated to be a valuable diene in Diels-Alder reactions. These processes provide new and effective routes to aromatic and cyclohexenone systems. The pathways by which the intermediate 3-methoxy-l-silyloxycyclohexenes are transformed to cyclohexenones are considered. © 1979, American Chemical Society. All rights reserved.

引用

页码：6996 / 7000

页数：5

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