A GENERAL SYNTHETIC ROUTE TO 2,2'-5',2''-TERPYRROLE, 2,5-BIS(2-PYRRYL)THIOPHENE, AND ALKYL-SUBSTITUTED ANALOGS

被引：55

作者：

MERRILL, BA ^{[1
]}

LEGOFF, E ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 09期

关键词：

D O I：

10.1021/jo00296a062

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new four-step route to 2,2':5',2“-terpyrroles (4,13) and 2,5-bis(2-pyrryl)thiophenes (6,14) is described. The key step involves a Stetter reaction between an electron-deficient pyrrole aldehyde and divinyl sulfone. The resulting symmetrical 1,4-diketone is used as a common precursor for the synthesis of both tricyclic systems. © 1990, American Chemical Society. All rights reserved.

引用

页码：2904 / 2908

页数：5

共 28 条

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