GEOMETRIC AND ELECTRONIC EFFECTS IN THE SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES OVER ZEOLITE-SUPPORTED METALS

被引：140

作者：

BLACKMOND, DG ^{[1
]}

OUKACI, R ^{[1
]}

BLANC, B ^{[1
]}

GALLEZOT, P ^{[1
]}

机构：

[1] CNRS,INST RECH CATALYSE,F-69626 VILLEURBANNE,FRANCE

来源：

JOURNAL OF CATALYSIS | 1991年 / 131卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9517(91)90275-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation of two α, β-unsaturated aldehydes, cinnamaldehyde and 3-methylcrotonaldehyde was investigated over Ru, Pt, and Rh. The use of zeolite supports was compared with activated carbon for Ru, and the effect of changing the neutralizing cation in the Y zeolite was compared for all three metals. Selectivity to the unsaturated alcohol could be influenced by both geometric and electronic effects, and the relative importance of these effects was found to depend on the nature of the organic substrate. © 1991.

引用

页码：401 / 411

页数：11

共 37 条

[1] PROMOTING EFFECTS OF ALKALINE CATIONS ON THE PD/Y CATALYZED METHYLCYCLOPENTANE CONVERSION
BAI, XL
SACHTLER, WMH
[J]. CATALYSIS LETTERS, 1990, 4 (4-6) : 319 - 325
[2] BLACKMOND DG, 1988, STUDIES SURFACE SCI, V38, P33
[3] BONACICKOUTECKY J, 1988, J CATAL, V111, P409
[4] RH/AIPO4 CATALYSTS .9. LIQUID-PHASE HYDROGENATION AND ISOMERIZATION OF ALPHA,BETA-UNSATURATED ALCOHOLS
CAMPELO, JM
GARCIA, A
LUNA, D
MARINAS, JM
[J]. JOURNAL OF CATALYSIS, 1988, 113 (01) : 172 - 184
[5] INSITU CHEMICAL TRAPPING OF CO/H-2 SURFACE SPECIES
CAVALCANTI, FAP
BLACKMOND, DG
OUKACI, R
SAYARI, A
ERDEM-SENATALAR, A
WENDER, I
[J]. JOURNAL OF CATALYSIS, 1988, 113 (01) : 1 - 12
[6] CORDIER G, 1988, Patent No. 882919
[7] CATALYTIC OXIDATIVE DEHYDROGENATION OVER CU-2+ EXCHANGED NAY AND KY ZEOLITES
COUGHLAN, B
KEANE, MA
[J]. CATALYSIS LETTERS, 1990, 4 (03) : 223 - 233
[8] A CATALYTIC AND CHARACTERIZATION STUDY OF THE SURFACE-ACIDITY GENERATED ON THE REDUCTION OF COPPER EXCHANGED Y-ZEOLITES
COUGHLAN, B
KEANE, MA
[J]. CATALYSIS LETTERS, 1990, 5 (02) : 113 - 126
[9] THE CATALYTIC DEHYDROGENATION OF CYCLOHEXANE AND METHYLCYCLOHEXANE OVER NICKEL LOADED Y-ZEOLITES
COUGHLAN, B
KEANE, MA
[J]. CATALYSIS LETTERS, 1990, 5 (02) : 89 - 100
[10] THE HYDROGENATION OF TOLUENE OVER NICKEL LOADED Y-ZEOLITES
COUGHLAN, B
KEANE, MA
[J]. CATALYSIS LETTERS, 1990, 5 (02) : 101 - 112

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