THE PREPARATION AND CRYSTAL-STRUCTURE OF FAC-[IR(TACN)CL3] (TACN=1,4,7-TRIAZACYCLONONANE) AND THE PREPARATION OF CS[IR(H2O)6](SO4)2.6H2O

被引：15

作者：

GAJHEDE, M ^{[1
]}

SIMONSEN, K ^{[1
]}

SKOV, LK ^{[1
]}

机构：

[1] UNIV COPENHAGEN,HC ORSTED INST,DEPT CHEM,UNIV PK 5,DK-1200 COPENHAGEN O,DENMARK

来源：

ACTA CHEMICA SCANDINAVICA | 1993年 / 47卷 / 03期

关键词：

D O I：

10.3891/acta.chem.scand.47-0271

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A procedure is given for the preparation of fac- [Ir(tacn)Cl3] (tacn = 1,4,7-triazacyclononane) from the iridium(III) alum, and a straightforward method for synthesis of Cs[lr(H2O)6](SO4)2 . 6H2O in good yield is also given. The crystal structure of fac- [Ir(tacn)Cl3] was determined by single-crystal X-ray diffraction (orthorhombic, Pna21, a = 12.0487(15), b = 7.969(2), c = 16.9735(11)angstrom, Z = 4).

引用

页码：271 / 274

页数：4

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