HELIUM DIFFRACTION STUDY OF THE NUCLEATION AND GROWTH OF PALLADIUM CLUSTERS ON MGO (100)

被引:27
作者
HENRY, CR [1 ]
MEUNIER, M [1 ]
MOREL, S [1 ]
机构
[1] UNIV AIX MARSEILLE 2,CRMC2,CNRS,PROPRE LAB,F-13288 MARSEILLE 09,FRANCE
关键词
D O I
10.1016/0022-0248(93)90475-C
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Helium diffraction is used for the first time to study the nucleation and growth of three-dimensional metallic clusters on a crystalline substrate. It is shown that from the attenuation of the first order diffraction peak from the MgO substrate it is possible to derive the growth rate and the nucleation kinetics of the Pd clusters. Transmission electron microscopy (TEM) observation of the final deposit allows one to determine the width of the diffuse scattering zone around the clusters. The first results obtained at two different substrate temperatures are analysed following the atomistic theory of nucleation and growth.
引用
收藏
页码:416 / 420
页数:5
相关论文
共 12 条
[1]   FORMATION AND CHARACTERIZATION OF SMALL PD PARTICLES DEPOSITED ON MGO AS A MODEL CATALYST [J].
CHAPON, C ;
HENRY, CR ;
CHEMAM, A .
SURFACE SCIENCE, 1985, 162 (1-3) :747-754
[2]  
CHEMAN A, 1986, THESIS MARSEILLE
[3]   STRUCTURAL CHARACTERIZATION OF MGO(100) SURFACES [J].
DURIEZ, C ;
CHAPON, C ;
HENRY, CR ;
RICKARD, JM .
SURFACE SCIENCE, 1990, 230 (1-3) :123-136
[4]   GROWTH AND MORPHOLOGY OF PALLADIUM PARTICLES EPITAXIALLY DEPOSITED ON A MGO(100) SURFACE [J].
HENRY, CR ;
CHAPON, C ;
DURIEZ, C ;
GIORGIO, S .
SURFACE SCIENCE, 1991, 253 (1-3) :177-189
[5]   DOES THE SURFACE-TEMPERATURE INFLUENCE THE CROSS-SECTION OF RANDOM ISOLATED ADSORBATES IN THERMAL HE SCATTERING [J].
POELSEMA, B ;
VERHEIJ, LK ;
COMSA, G .
SURFACE SCIENCE, 1984, 148 (01) :117-125
[6]  
Poelsema B., 1989, SPRINGER TRACTS MODE, V115
[7]   NUCLEATION OF METAL CRYSTALS ON IONIC SURFACES [J].
ROBINS, JL ;
RHODIN, TN .
SURFACE SCIENCE, 1964, 2 :346-355
[8]  
SANCHEZ A, 1987, SURF SCI, V187, pL587, DOI 10.1016/S0039-6028(87)80106-1
[9]   MONTE-CARLO SIMULATION OF THE NUCLEATION AND GROWTH OF BINARY-ALLOY PARTICLES OF AU, AG, AND PD ON NACL(100) SUBSTRATES [J].
SCHMIDT, A ;
SCHUNEMANN, V ;
ANTON, R .
PHYSICAL REVIEW B, 1990, 41 (17) :11875-11880
[10]  
STOYANOV S, 1981, CURRENT TOPICS MATER, V7, P69