EVALUATION OF A DELAYED COKING PROCESS BY H-1 AND C-13 NMR-SPECTROSCOPY .2. DETAILED INTERPRETATION OF LIQUID NMR-SPECTRA

被引:14
作者
RODRIGUEZ, J [1 ]
TIERNEY, JW [1 ]
WENDER, I [1 ]
机构
[1] UNIV PITTSBURGH,DEPT CHEM & PETR ENGN,PITTSBURGH,PA 15261
关键词
COKING PROCESS; DELAYED; NMR SPECTRAL;
D O I
10.1016/0016-2361(94)90214-3
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The H-1 and C-13 nuclear magnetic resonance (n.m.r.) spectra of a delayed coking feedstock and products, presented in a previous paper, are analysed here in detail by matching results from inspection of both nuclei. The conventional spectra of whole samples are used in combination with elemental analysis data, and substantial agreement is obtained. Differences are explored to yield valuable information. Interpretation of some band assignments is modified to account for new results. This approach results in a detailed quantitative estimation of a few key structures that contain the main functional groups that characterize these petroleum fractions.
引用
收藏
页码:1870 / 1875
页数:6
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